Numbering Code	U-ENG25 35120 LJ75	Year/Term	2022 ・ Second semester
Number of Credits	2	Course Type	Lecture
Target Year		Target Student
Language	Japanese	Day/Period	Wed.2
Instructor name	KAWAI JIYUN (Graduate School of Engineering Professor)
Outline and Purpose of the Course	Quantum spectrochemistry, which is a basis of spectrochemical analysis, will be lectured. Various kinds of spectrometries which are used in materials analysis will also be explained.
Course Goals	The goal of the course is to obtain knowledges about quantum chemistry, interaction between photons and electrons, spin, principles of spectrometers, quantum mechanical calculations related to spectroscopy, and so forth, which are necessary for spectrochemical analysis.
Schedule and Contents	1. Quantization,1time,Bragg diffraction equation deduced from Bohr-Sommerferd quantization. Compton scattering equation explained from both wave and particle views. 2. Principle of least action,2times,Refraction of electron beam. Phase velocity and group velocity. Spin and helicity of photon. Polarization of light. Inertial mass and gravitational mass of photon and its relation to Maessbauer spectroscopy. Zeeman effect. 3. Matrix mechanics,1time,Scheroedinger equation. Matrix mechanics. Role of harmonic oscillator in atomic spectra. 4. Perturbation theory,2times,Time independent perturbation theory applied to ionic crystal. 5. Optical transition,2times,Blackbody radiation. Time dependent perturbation. Tsallis entropy. Electric dipole transition. 6. Harmonic oscillator,1time,Harmonic oscillator. WKB approximation. Field quantization. 7. Electron spectroscopy,1time,Photoelectron spectroscopy of transition metal compounds. Configuration interaction. 8. Symmetry,1time,Symmetry of molecules. Group theory. Projection operator. 9. Interaction between electrons and photons,2times,IR and Smekal-Raman spectroscopy. 10. Angular momentum and spin,1time,Angular momentum and spin. Spin-orbital interaction. 11. Check of achievement,1time,
Evaluation Methods and Policy	Checked only by exam.
Course Requirements	None
Study outside of Class (preparation and review)	The homework will be announced in the lecture.
Textbooks	Textbooks/References	量子分光化学，増補改訂版, 河合潤, (アグネ技術センター，2015), ISBN:9784901496759 J. Kawai, "Quantum Spectrochemistry", 2nd Edition, AGNE Gijutsu Center, Tokyo (2015).(ISBN:9784901496759) isbn{}{9784901496759}
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