Radiochemistry

Numbering Code U-ENG25 35116 LJ60
U-ENG25 35116 LJ77
Year/Term 2022 ・ Second semester
Number of Credits 2 Course Type Lecture
Target Year Target Student
Language Japanese Day/Period Mon.1
Instructor name SASAKI TAKAYUKI (Graduate School of Engineering Professor)
TAISHI KOBAYASHI (Graduate School of Engineering Associate Professor)
Outline and Purpose of the Course Lectures on the use of radionuclides, recycling of spent fuel and disposal of radioactive waste, physicochemical fundamentals related to the reactivity of radioactive materials, and essential analytical methods for material state analysis.
Course Goals The course objective is to develop an understanding of the physicochemical properties and reactivity of radioactive materials, and to learn the latest research and engineering applications based on these principles.
Schedule and Contents The main contents of each class session are as follows:

1) Atoms, nuclei, and isotopes
2) Mass, decay and half-life, radiation equilibrium
3) Nuclides, dating, tracer chemistry
4) Dilution analysis, NAA
5) Cross-section, application (analysis, radiation source)
6) Nuclear fuel cycle
7) Cycle engineering: nuclear fuel, smelting, compounds
8) Overview of geological disposal (advance dispersion, chemical equilibrium)
9) Actinide chemistry
10) Chemical analysis and spectroscopy of actinide and fission products
11) Chemical thermodynamics (complexation, solubility)
12) Electrochemistry (redox, electric double layer)
13) Reprocessing (extraction equilibrium, extractant, countercurrent distribution)
14) Waste treatment (ion exchange reaction, membrane equilibrium)
15) Feedback; confirmation of learning achievement
Evaluation Methods and Policy Grading is based on the score of the periodic evaluations. Students will be evaluated based on their demonstrated understanding of the physicochemical properties and reactivity of radioactive materials and the engineering processes involved.
Course Requirements N/A
Study outside of Class (preparation and review) Focusing on reviewing lecture content and exercises is advisable.
Textbooks Textbooks/References Other materials are not specified. Handouts, etc. will be distributed during lectures.
References, etc. Other, Radiochemistry and Nuclear Chemistry, 4th ed., G. R. Choppin et al., Elsevier (2013) isbn{9780124058972};
Nuclear Chemical Engineering, 2nd Ed., M. Benedict et al., McGraw-Hill (1981) isbn{0070045313}, etc.
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