Chemistry of Organometallic Complexes
| Numbering Code | G-ENG13 5H210 LJ60 | Year/Term | 2022 ・ Second semester | |
|---|---|---|---|---|
| Number of Credits | 1.5 | Course Type | Lecture | |
| Target Year | Target Student | |||
| Language | Japanese | Day/Period | Tue.2 | |
| Instructor name | FUJIHARA TETSUAKI (Graduate School of Engineering Associate Professor) | |||
| Outline and Purpose of the Course | Basic organometallic chemistry including history, structure, bonding, reactions, and survey of various metal complexes is lectured. Several typical catalytic reactions are explicated on the basis of elementary steps in organometallic chemistry such as ligand substitution, oxidative addition, reductive elimination, and insertion reactions. | |||
| Course Goals |
Acquirement of basic idea of: 1. General properties of transition metal organometallic complexes 2. Reactivity of transition metal organometallic compounds 3. Homogeneous catalysis of practical importance 4. Recent research trends in homogeneous catalysis |
|||
| Schedule and Contents |
Introduction,1time,History Application Research trends Zaise salt Grignard reagent Alkyl lithium Ferrocene General properties of organometallic complexes ,1time,Bonding Structure in general Coordination number η-Structure μ-Structure Organometallic seminar (1),1time,Number of d- and s-electrons Classification and the nature of ligands Effect of complexation Formal charge Electron counting 18-electron rule Oxidation state General properties and reactivities of transition metal organometallic complexes,3times,Several important steps in transition-metal complex catalyzed reactions are discussed, including coordination, oxidative addition, insertion, reductive elimination. Recent research trends in homogeneous catalysis (1),1time,Wacker process Various cross-coupling reaction Mizoroki-Heck reaction Recent research trends in homogeneous catalysis (2),1time,C-H and C-C bond activation Organometallics in materials science (1),2times,Asymetric catalysis Organometallics in materials science (2),1time,Strucural metarials Organometallic seminar (2),1time,Electronic and optoelectronic applications |
|||
| Evaluation Methods and Policy | Graded by written examination | |||
| Course Requirements | Basic knowledge in organic chemistry, physical chemistry, and inorganic chemistry is requisite. | |||
| Textbooks | Textbooks/References | No textbooks are used. | ||
| References, etc. | R.H.Crabtree,The Organometallic Chemistry of the Transition MetalsFourth Edition;Wiley-Interscience:Hoboken,2005. | |||
| Related URL | ||||
